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Dissolved oxygen

Water is an oxygen poor environment. It contains only 5% of the oxygen that the same volume of air does:

  • 1 litre of oxygen weighs 1,428mg
  • 1 litre of air contains 285mg oxygen
  • 1 litre of freshwater contains 14.6mg oxygen at 0°C

Oxygen is depleted by:

  • plants at night
  • livestock
  • biological filtration

Oxygen is replenished by:

  • plants during the day
  • diffusion at air-water interfaces

Oxygen and saturation

If a beaker of sterile freshwater is left to stand at 25°C then the normal maximum amount of oxygen that it can dissolve is 8.2mg/litre. At this point the water sample is said to be SATURATED. If it contained only 4.1mg/l then it would be 50% saturated. A level of dissolved oxygen of 6mg/l as recommended in the OATA "Water Quality Criteria" is equivalent to 73% saturation.

Solubility of oxygen

As the table below demonstrates, that as the water temperature rises the amount of oxygen it may dissolve before becoming saturated diminishes. Seawater dissolves less oxygen than freshwater before it becomes saturated. Altitude and atmospheric pressure play a small part in determining oxygen solubility. For practical purposes both may be ignored.

Temp °C mg/l oxygen freshwater OATA criteria in terms of % saturation mg/l oxygen saltwater OATA criteria in terms of % saturation
0
5
10
15
20
25
30
14.6
12.8
11.3
10.1
9.1
8.2
7.5
41
47
53
59
66
73
80
11.7
10.4
9.3
8.5
7.8
7.1
6.5
47
52
58
65
71
77
85

Oxygen and the weather

The weather may combine all of the factors to create problems (some of them may arise also in fish houses).

  • Sunlight
    Sunlight increases water temperature and hence decreases oxygen solubility.
  • Freezing
    Ice seals the surface preventing the entry of oxygen and the escape of toxic gases.
  • Still periods
    When there is little wind such as before thunder storms, the rate of diffusion of oxygen is diminished by the reduction of the pond surface area (ripples in a light wind may increase the surface area of a pond by two or three times).

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